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1. Consider the reaction described by the equation Cr(H2O)63+ (aq) + SCN- (aq) → Cr(H2O)5SCN2+ (aq) + H2O(1)
For which the following initial-rate data were obtained at 25°C:
[Cr(H2O)63]0 (M)
[SCN-]0 (M)
Initial rate (M/s)
1.0x10-4
0.10
2.0x10-11
1.0x10-3
2.0x10-10
1.5x10-3
0.20
6.0x10-10
0.40
1.2x10-9
(a) Determine the rate law and the value of the rate constant for the reaction.
(b) If the rate constant at 50°C is found to be 2x10-5 M-1 s-1, what is the activation energy of this reaction?
(c) If a catalyst were used, what do you expect to happen with the activation energy?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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