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1) Heroin is 3, 6-diacetylmorphine. Heroin is 2-3 times more potent than morphine.
In vitro and in vivo, to which product does heroin hydrolyze first, (3- or 6-acetylmorphine), and why?
Hint: What are the acidic pKa values of the respective hydroxyl products? Look up the structures on the internet or use the UF library online e-journals.
2) Acetylsulfisoxazole, is readily hydrolyzed in vivo to sulfisoxazole. On the other hand, the acyl group in amikacin, is stable to hydrolysis in vivo. Both N-acetylsulfisoxazole and N-acetylamikacin are acyl derivatives where the acyl group is attached to nitrogen.
Why is one stable and the other not?
Hint: What are the acidic pKa values of the respective N-H groups formed on hydrolysis. Look up the structures on the internet or use the UF library online e-journals.
Compute the concentration of IO3- in a 5.92 mM Pb(NO3)2 solution saturated with Pb(IO3)2. The Ksp of Pb(IO3)2 is 2.5 × 10-13. Presume that Pb(IO3)2 is a negligible source of Pb2 compared to Pb(NO3)2.
What mass of methane do you have to burn to heat the airfrom 15. degrees C to 22.0 degrees C
chloroform is a common liquid used in the laboratory. it vaporizes readily. if the pressure of chloroform vapor in a
The flask shown here contains 0.214 g of acid and a few drops of phenolphthalein indicator dissolved in water. The buret contains 0.310 M NaOH. What volume of base is needed to reach the end point of the titration
Propose and state the mechanism for the reaction that occurs between 2-methyl-2 propanol as well as NH4Cl in an H2SO4/H2O medium.
what is the total volume of air in a room which contains a total of 75 kG of oxygen?
Some solid remained in the beaker after stirring with HCl. You washed the filter paper with ketone, which caught on fire and the filter paper was scorched
At 25°C and 1.00 atm pressure, one liter of ammonia is bubbled into 725 mL of water. Assume that all the ammonia dissolves and the volume of the solution is the volume of the water
How many electrons in an atom could have these sets of quantum numbers? A) n=3, B) n=5, l=0 and C) n=6, l=1, ml=-1
for the equilibriumh2g co2 g lt--gt h20 g cogkc 3.18 at 1106k. if each of the four species was initially present at a
The addition of 25.40g of an unknown metal at 90.0 C to 20.00g of water at 22.3C resulted in a final maximum temperature of the system of 26.8 C. Compute he specific heat of the metal.
The heat of solution of ammonium chloride is 15.2 kJ/mol. If a 6.134 g sample of NH4Cl is added to 65.0 mL of water in a calorimeter at 24.5°C, what is the minimum temperature reached by the solution?
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