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Many proteins contain metal porphyrin molecules that can be modeledas a planar square with an edge length of 10A. The π systemcan be described as electrons in a box.
1. Write down the schroedinger equation for the square and find theeigenvalue sand eigenfunctions of the system.
2. Use the electron mass 9*10^-31 kg and h = 10^-34 Js and thelength of the edge of the square to determine the energy levels incm^-1 as a function of the two indicies nx andny for the particle in a square. (it is recommended towork first with a single system in m/kg/s and then convert theresults to cm^-1.
3. Electrons enter the wavefunctions as pairs. Ie to everywavefunction we can put two electrons and we start with the lowestenergy states and go up. The heme has 18 electrons. What is the lowest energy absorption (moving electron from occupied to emptyorbital) that we can have in the mode? ( experimentally theexcitation is of 17,000 cm^-1)
What concentration of chloroacetic acid, ClCH2COOH, should be added to a 0.010 M ClCH2COONa solution to prepare a buffer of pH 4.00? Ka = 1.4 X 10-3
a 14.0-g sample of cacl2 is dissolved in 112 g of water with both substances at 25.0degc. calculate the final
When waves of equal amplitude from two sources are out of phase when they interact, it is called __________. a) destructive interference b) diffraction c) constructive interference d) effusion e) amplitude
A 10.80-mL sample of sulfuric acid from an automobile battery requires 35.18-mL of 1.62 M sodium hydroxide solution for complete neutralization. What is the molarity of the sulfuric acid? Sulfuric acid contains two acidic hydrogens.
Complexes of a given metal with ligands higher in the spectrochemical series like CN- will display _______ crystal-field splitting and will absorb light towards the ____ end of the spectrum.
Alkynes can be hydrated in the presence of acid and HgSO4, by electrophilic addition of a molecule of water to the triple bond.
Draw and exlpain using representation of molecular orbitals the structure and bonding found in ethane; indicate clearly the structure
Describe the hybrid orbitals used by the central atom in O 3 .and also determines what is the number of sigma and pi bonds present in O 3 .
Just transfer this solution completely to a flask of 1L volumetric and dilute to exactly 1 liter and then compute the Fe 2+ ion concentration.
1. which hasthe higher boiling point hf or hcl? why?2. potassiummetal crystallizes in a body-centered cubic structure
After the reaction was comlete, the volume of the dry has produced was 1 liters at 75 degrees celsuis and 721 torr. what was the percent potassium notrate in the original sample?
What is the coefficient of H2O when the following equation is properly balanced with the smallest set of whole numbers
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