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CH3402: Frontiers in Ligand Design and Coordination Chemistry
Knowledge• Show an awareness of the electronic properties of the s, p, d, and f block metals.• Show an awareness of how ligand structure influences the structure of metal complexes.• Appreciate the reactivity of metal complexes, and how this can be influenced by changes in the supporting ligands.• Identify structure-activity relationships in coordination complexes, particularly focussing on ligand structure and coordination geometry vs. reactivity.
Understanding• Relate the electronic structure of metals to the observed reactivity of metal complexes.• Understand the properties of ligands, and how design features can be used to control the properties of metal complexes.• Understand the dynamic nature of many metal complexes, and relate this to observed reactivity patterns.
Discipline-Specific Skills• Appreciate and understand how metal complexes can be employed as homogeneous catalysts;• Understand the fundamental organometallic reactions that underpin homogeneous catalysis;• Understand how experimental data and spectroscopic methods can be used to deduce the catalytic cycle.
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