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1. Treatment of ethyl isobutyrate with ethoxide in ethanol, followed by mild acidic workup, leads to recovery of starting material rather than a Claisen Condensation product. Please explain this observation, using structures rather than words as much as possible.
2. The Wieland-Miescher ketone is an important starting point for the synthesis of biologically active steroid derivatives. It is prepared via a reaction called the Robinson Annulation (which tends to show up on the MCAT). Please provide a detailed arrow-pushing mechanism for this reaction.
if 25.0 mL of 0.125 M HCl is neutralized by exactly 14.8 mL of NaOH, what is the concentration of the base?
What is the vapor pressure of each of the solution components in the mixture? What is the total pressure above the solution?
When 79.272 cg of nitrogen gas is reacted with 79.272 cg of hydrogen gas, how many grams of ammonia are formed?
How many moles of PCl_5 can be produced from 21.0 g of P_4 and excess Cl_2?
When determining the number of milliliters of mercuring with the density of 13.6 g/mL and having a mass of 501 g, do you divide 13.6 by 501?
What is the theoretical yield of chromium that can be produced by the reaction of 40.0 g of Cr2O3 with 8.00 g of aluminum according to the following equation?
For the reaction 2C6H6 + 15O2 → 3CO2 + 6H2O 30 grams of C6H6 are allowed to react with 79.09 grams of O2.
A camera falls from a blimp that is 485 m above the ground and rising at a speed of 16.8 m/s. Find the maximum height reached by the camera with respect to the ground. The acceleration of gravity is 9.8 m/s2
A 500.0 g sample of aluminium is initially at 25.0 °C. It absorbs 32.60 kJ of heat from its surroundings. What is its final temperature, in °C? (specific heat = 0.9930 J g-1 K-1 for aluminum)
In 13C NMR, splitting of spectral lines is due to: A) coupling between a carbon atom and protons attached to that carbon atom b) coupling between a carbon atom and protons attached to adjacent carbon atoms
Calculate the mass of silver chloride required to plate 235 mg of pure silver. Silver chloride, often used in silver plating, contains 75.27% .
Calculate deltaS(Jmol^-1K^-1) for oxalic acid and delta S (Jmol^-1K^-1) for the combustion of one mole of oxalic acid.
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