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1)A coffee cup calorimeter was used for the neutralization reaction of 100 mL of 1.00 M hydrochloric acid with 100 mL of 1.20 M sodium hydroxide. The initial temperature was 22.88 °C and the final temperature was 29.39 °C. Calculate the calorimeter constant for the reaction. HCl (aq) + NaOH (aq) NaCl (aq) + H2O (?H°rxn = -58.3 kJ/mol)2)The same calorimeter was used for the dissolution of 8.86 g sample of lithium chloride in 100.0 mL of water at 22.2 °C. When the salt was dissolved, the temperature of the solution was 39.5°C. Calculate the molar enthalpy of solution of lithium chloride. Is the dissolution of lithium chloride endothermic or exothermic? [The density of water is 1.0 g/mL.]
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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