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The molar volume (cm3/mol) of a binary liquid mixture is given by:
V= 120 x1+ 70x2 + ( 15x1 + 8x2) x1x2
Find the expressions for the partial molar volumes of species 1 and 2.
Problem 2:
2. The reaction Aà B takes place in an ideal gas at 349 K and 1 atm. At these conditions, the Gibbs free energy of species A is 1000 J/mol, and the Gibbs free energy of species B is 400 J/mol. Initially, 1 mol of A is present.
a. Express the total Gibbs free energy of the ideal gas mixture as a function of the extent of reaction alone.
b. Plot the total Gibbs free energy as a function of the reaction extent. What is the extent at equilibrium?
c. What is the equilibrium conversion of species A?
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