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Assuming that in free-radical polymerization the rate constants can be replaced by the appropriate Arrhenius expressions:
kd = Adexp(-Ed/RT)
kp = Apexp(-Ep/RT)
kt = Atexp(-Et/RT)
Calculate the changes in the rate of polymerization and the degree of polymerization caused by increasing the temperature of polymerization of styrene in benzene initiated by AIBN from 60C to 70C given that:
Ep = 34 kJ mol-1
Et = 10 kJ mol-1
Ed = 126 kJ mol-1
Assume that the concentration of monomer and initiator and the values of f and q remain unchanged when the temperature is increased.
How can glycine act as a buffer at pH 6.00 and why? Please use chemical equations to show how it can act as a buffer at this pH specifically?
Silver chloride, often used in silver plating, contains 75.27% . what is the mass of silver chloride required to plate 285 of pure silver
If the density of water is 1.00g/mL, what is the weight in pounds of gallon of water? you may assume that mass and weight are equivalent at the earth's surface.
write a balanced molecular equation for mnso4xh2o reacting with h2c2o4 and water to form mnc2o4x3h2o. what will be the
A solution contains .294 M solution sodium cyanide and .0919 M hydrocyanic acid. What is the pH of this solution.
liquid water and sealed at 25C and a pressure of 1.00 bar. What is the pressure if the temperature of the system is raised to 60.0C?
for many material applications the mass density is an important parameter particularly in the transportation industry.
Calculate the molar mass of the compound if given that normal freezing point of C6H6 = 5.5 oC , the freezing point depression constant for C 6 H 6 = -5.12 o C/m .
under what conditions of pressure and temperature do real gases most closely approximate ideal-gas behavior?a name the
Calculate the number of moles of solute present in 50.0mg of aqueous solution that is 1.25 molality NaCl.
if the pressure of chloroform vapor in a flask is 154 mm hg at 25.0degc and the density of the vapor is 1.25 gl what is
Acetic Acid is a weak acid with a Ka value of 1.8x10^-5. What concentrationof acetic acid is needed to produce a [H+] of 3.5x10^-4?
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