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1. Consider the effect of adding 1.0 mL of 1.0 M NaOH to 1.0 L of water. What is the pH of this solution before and after addition of base?
2. Consider the effect of adding 1.0 mL of 1.0 M NaOH to 1.0 L of a buffer that contains 0.1 M HC2H3O2 and 0.1 M NaC2H3O2. What is the pH before and after the addition of base?
3. Which of the following acids would be there best choice to combine with its sodium salt to make a solution buffered at pH 3.45? For the best choice, calculate the ratio of the conjugate base to the acid required to attain the desired pH.
Chlorous acid pKa = 1.95Nitrous acid pKa=3.34Formic acid pKa= 3.74Hypochlorous acid pKa = 7.54
4. Which of the acids in question #3 would be the best choice to create a buffer with pH = 7.35? If you had 250.0 mL of a 0.20 M solution of the acid, what mass of the corresponding sodium salt of the conjugate base would be required to make the buffer? (assume addition of the solid salt would not affect the volume of the solution)
5. A 1.0 L buffer solution is 0.10 M in HF and 0.050 M in NaF. Which of the following actions would destroy the buffer?
a) Adding 0.050 mol of HClb) Adding 0.050 mol of NaFc) Adding 0.05 mol of NaOHd) None of the abovee) More than one of the above
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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