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A storage tank for liquid n-octane has a diameter of 30 ft and a height of 20 ft. During a typical 24-h period the level of liquid octane falls from 18 ft to 8 ft. after which fresh octane is pumped into the tank to return the level to 18 ft. As the level in the tank falls, nitrogen is fed into the tree space to maintain the pressure at 16psia; when the tank is being refilled, the pressure is maintained at 16psia by discharging gas from the vapor space to the environment. The nitrogen in the tank may be considered saturated with octane vapor at all times. The average tank temperature is 90°F.
(a) What is the daily rate, in gallons and lbm, at which octane is used?
(b) What is the variation in absolute pressure at the bottom of the tank in inches of mercury?
(c) How much octane is lost to the environment during a 24-h period?
(d) Why is nitrogen used in the vapor space of the tank when air would be cheaper?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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