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A 30-mL volume of a K2HPO4 solution containing 50-mg P/L is placed in contact with 40g of soil (dry weight basis) in a centrifuge tube. After a 7-d equilibration period, the suspension is centrifuged to separate the equilibrium solution from the soil. A 5-mL aliquot of this equilibrium solution is diluted with 45 mL of a 10mM CaCl2 solution. The diluted solution is analyzed for P and found to contain 1.0 mg P/L. Answer the following:
What is the concentration of P retained in the soil (in mg P/kg)?
What is the concentration of PO4 retained by the soil (in mg PO4/kg)?
What was the molecular concentration of P in the initial solution (before placing in contact with the soil)?
What was the molecular concentration of K2HPO4 in the initial solution?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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