State the structures of the disulfides

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The structures of the disulfides (MS2) show an apparently unusual trend, proceeding from left to right across the transition series. On the left side (TiS2, ZrS2, MoS2, etc.), one finds layered structures, whereas in the middle (ReS2, FeS2, RuS2) there are three-dimensional pyrite- and marcasite-type structures. On the right (PtS2, SnS2), there are again layered structures. Briefly explain these trends.

Reference no: EM13165749

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