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A rigid tank of volume 0.5 m^3 is connected to a piston cylinder assembly by a valve, as shown below. Both vessels contain pure water. They a re immersed in a constant-temperature bath at 200°C and 600 kPa. Consider the tank and the piston-cylinder assembly as the system and the constant-temperature bath as the surroundings. Initially the valve is closed and both units are in equilibrium with the surroundings (the bath). The rigid tank contains saturated water with a quality of 95% (i.e., 95% of the mass of water is vapor). The piston-cylinder assembly initially has a volume of 0.1 m^3. The valve is then opened. The water flows into the piston-cylinder until equilibrium is obtained. Determine the work done, W, by the piston, the change in internal energy, U, of the system and the heat transferred, Q. Also calculate the total change of entropy for this process.
An aqueous antifreeze solution is 35.0% ethylene glycol (C2H6O2) by mass.
The equilibrium concentration of HA will be less than the stoichiometric concentration because some or all of HA ionizes.
The chemical reaction that causes aluminum to corrode in air is given by 4Al+3O2 Al2O3 in which Hrxn = %3352 kJ rxn = %u2212625.1 J/K) What is the Gibbs free energy for this reaction at 5975K ?
when separated from a water solution CuSO4 forms a hydrate with 5 wlater molecules per formula unit. if 47 g of anhydrous CuSO4 are dissolved in water, what mass of the hydrate could be recovered from the solution.
30.0 mL of 0.150 M CH3CO2H are titrated with 0.150 M NaOH. What is the pH of the solution after 15.0 mL of NaOH has been added. The Ka for acetic acid is 1.80 x 10-5
The compression ratio of today's cars is so much higher than in cars of years past. What is the major advantage of increasing the compression ratio?
a perfect gas undergoes isothermal compression which reduces its volume by 2.20 L. the final pressure and volume of the gas are 3.78x10^3 torr and 4.65 L, respectively
Important information about Molar concentrations, Calculate the molar concentrations, I-, disulfur octaoxide, disulfur trioxide.
In the preparation of the esters given in this experiment, the reaction product was extracted with 5% sodium bicarbonate solution in the isolation step. Why? What gas was evolved during this washing step? Write a balanced equation for the reaction..
At 0.0 C, if the volume of air is 2 mL and the pressure of the atmosphere that day is 665 mmHg, what is the number of moles of air?
Calculate the volume of C2H2 that is collected over water at 23 Celcius by reaction of 0.751 g of CaC2 if the total pressure of the gas is 740 torr. (The vapor pressure of water is 21.07 torr .)
The latent heat of vaporization of water is 577 J/kg. If a person's body needs to lose 345 J of energy through sweating, how many kilograms of water in the form of sweat must be evaporated.
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