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The CO2 produced in one round of the citric acid cycle does not originate in the acetyl carbons that enter that round. Create a diagram of the TCA cycle to illustrate the answers to questions 1a and 1b.
a. If acetyl-CoA is labeled with 14C at its carbonyl carbon, how many rounds of the cycle are required to produce 14CO2?
b. How many rounds if acetyl-CoA is 14C-labeled at its methyl group?
You must show the carbon cycling to get full credit.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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