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A) (25 pts) Consider a 1.00 mol sample of acetylene (C2H2) is allowed to undergo the following two step, reversible process: the gas is a) first heated at constant volume until its pressure increases from 2.5 atm to 3.2 atm and then b) cooled at constant pressure until its volume changes from 4.0 L to 2.2 L. Given that for acetylene that CP,m = 43.93 J•mol-1 • K-1 and that 1 L-atm = 101.325 kJ, determine the following: i) the work for step a) of the process (in kJ ) ii) the work for step b) of the process (in kJ) iii) the heat associated with step a) of the process (in kJ ) iv) the heat associated with step b) of the process (in kJ) v) the change in internal energy (?E) for the entire process (in kJ)
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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