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1) What observed rotation is expected when a 1.02 M solution of (R)-2-butanol is mixed with an equal volume of a 0.510 M solution of racemic 2-butanol, and the resulting solution is analyzed in a sample container that is 1 dm long? The specific rotation of (R)-2-butanol is -13.9 degrees mL g-1 dm-1.
2)An aqueous solution containing 6.07 g of an optically pure compound was diluted to 500.0 mL with water and placed in a polarimeter tube 20.0 cm long. The measured rotation was -3.69° at 25 °C. Calculate the specific rotation of the compound.
If 0.500 g of antacid was added to 50.00 mL of 0.100 M HCL and 5.65 mL of 0.100 M NaOH was required to titrate the un-neutralized HCL, calculate the actual neutralizing capacity of the antacid in mmol H+ per gram.
draw the organic product you would expect to obtain from reaction of the following model triglyceride
The addition of iodide (NaI or KI) often catalyzes SN2 reactions o alkyl chlorides or bromides. explain how by showing reaction equations of what happens.
Calculate the volume of concentrated reagent required to prepare the diluted solutions indicated.
A sample of hydrogen gas occupies 15.8 L at STP. How many moles of the gas are present?
Consider a glass of 215 mL of water at 28°C. Calculate the mass of ice at -15°C that must be added to cool the water to 10°C after thermal equilibrium is achieved.
Calculate the corresponding entropy for each state. d) Calculate the temperature for each state.
A graduated cylinder contains 145mL of water. A 10.0g piece of iron (density = 7.86g/cm3 ) and a 22.0g piece of lead are added.
Calculate the percent manganese in the sample as Mn3O4 (only part or none of the manganese may exist in this form, but we can make the calculations on the assumption that it does)
Consider a solution formed by mixing 61.0 mL of 0.100 M H2SO4, 26.0 mL of 0.100 M HOCl, 25.0 mL of 0.200 M NaOH, 25.0 mL of 0.100 M Ca(OH)2, and 10.0 mL of 0.150 M KOH.
if a gas 25.0 c occies 3.60 liters at pressure of 1.00 atm, what will be its volume at a pressure of 2.50 atm
Light with a frequency of 7.11 x 10 -14 Hz lies in the violet region of the visible spectrum. What is the wavelength of this frequency of light? Answer in units of nm.
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