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In 1978, scientists extracted a compound with antitumor and antiviral properties from marine animals in the Caribbean Sea. During elemental analysis of this compound, a 2.52 mg sample of the compound, didemnin-C, was found to give, upon combustion, 5.680 mg of CO2, and 1.823 mg of H2O. In another analytical method, the second sample of 2.52 mg of didemnin-C produced 0.254 mg of NH3. The molar mass of didemnin-C was found to be 1014 g x mol -1. What is (a) empirical and (b) molecular formula of didemnin-C? Note: While cytotoxicity, antiviral activity, and immunosuppressant properties of didemnin-C and of its 8 analogs were excellent to very good, these compounds were, unfortunately, dropped from further studies and development at the stage of human trials, as they produced very strong and serious side effects.
A solution is made by dissolving 21.5 grams of glucose (C6H12O6) in 255 grams of water. What is the freezing-point depression of the solvent if the freezing point constant is -1.86 °C/m?
What is the heat change in J associated with 74 g of gaseous butane at 91 oC changing to solid at -170 oC? c(butane) (gas) = 2.31 J/ (g.K) c(butane) (liq) = 1.65 J/(g.K) c(butane) (s) = 1.32 J/ (g.K) ?Hfus(butane) = 6.885 kJ/mol
What is the boiling point of the solution produced by adding 363 g of ethylene glycol (molar mass = 62.1 g/mol) to 1.5 kg of water? For each mole of nonvolatile solute, the boiling point of 1 kg of water is raised 0.51°C.
The equilibrium constant Kp for the reaction ; CCl4(g) C(s) + 2Cl2(g) at 700 celcius is 0.76 atm. Determine the initial pressure of carbon tetrachloride
Sulfuric acid (H2SO4) is a very strong diprotic acid. If 0.066 moles of sulfuric acid is mixed with water to make 192 mililiter of solution, what is the molarity of H+?
suppose a can contains gas at a pressure of 755 mm Hg and a temperature of 25 degrees celsius, what would be the pressure if the can was heated to 1155 degrees celsius ?
Calculate the pressure difference between CH4 and an ideal gas under these conditions. The van der Waals constants for CH 4 are a=2.300L2⋅atm/mol2 and b=0.0430 L/mol.
A solution is prepared by dissolving 14.4 g ammonium sulfate in enough water to make 100.0 mL of stock solution. A 11.50 mL sample of this stock solution is added to 55.00 mL of water.
We use Use the De Broglie wavelength formula, ohr radius definition and wave-particle duality equation to compute the wavelength of,
A steel tank with a volume of 9.583 L contains N2 gas under a pressure of 4.972 atm at 31.8 °C. Calculate the number of moles of N2 in the tank.
Calculate the pH of each of the following strong acid solutions: 5.00 mL of 1.00 M HCl diluted to 0.500 L d) a mixture formed by adding 50.0 mL of 0.020 M HCL to 150 mL of 0.010 M HI
What is the calculated value of the partial pressure(atm) of O2 in acid mine water of pH 1.700, in which [Fe3+] = [Fe2+]?
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