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Ttitrating 25.00 mL of 0.0400 M H2A with 0.100 M NaOH solution. Given Ka1= 3.16x10^-3 and Ka2= 5.01x10^-8 for H2A, Answer the following questions:
Just like the Henderson-Hasselbalch equation can be used during the buffer regions, the equation below can be used at the first equivalence point and greatly simplifies the problem.
pH = 1/2 (pKa1 + pKa2)
1. Write out the reactions and the equilibrium expressions associaed with Ka1 and Ka2.
2. Determine the pH at the following volumes of titrat added: A.0.00mL B. 5.00 mL C. 10.00 mL D. 15.00 mL E. 20.00 mL F. 25.00 mL
3. Identify the amphoteric substance in this process.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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