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You have been asked to analyze some mineral water for magnesium by standard addition using atomic absorption (AAS). You are given 100.0 ml volumetric flasks and 1.000 ml volumetric pipettes. The mineral water has a stated value of 20 ppm Magnesium. The maximum linear reading of the AAS system is 0.300 absorbance units which occurs at 0.600 ppm of Mg. Design a standard addition experiment using 5 flasks similar to that illustrated in Figure 5-7 of Harris. You have a 10.00 ppm stock solution of Mg. Include the following: a. Specify the volume of mineral water to add to each of the five flasks. b. Specify the volume of stock magnesium solution in each flask. c. Assuming the "true" value for Mg in the mineral water is 18 ppm compute the final concentration of magnesium in each of the flasks. d. Verify that no solution exceeds the linear range. You may do this by computing the expected absorbance of each solution from the data provided. e. What mass of magnesium do you need to make 1.000 L of 10.00 ppm stock solution. f. Incorporate items a - c into a short written procedure that you believe someone else could follow in the lab.
A certain second-order reaction ( B--> product) has a rate constant of 1.50×10?3 M-1*S-1 at 27C and an initial half-life of 214s. What is the concentration of the reactant B after one half-life
Which of the following terms would be used in a description of the mechanism of this reaction? tertiary carbanion, 2-methylpentoxonium ion, sp hybridized pentyne, vicinal dihydroxide, or hydroxide ion.
A 100-watt lightbulb radiates energy at a rate of 100 J/s.(The watt, a unit of power, or energy over time, is defined as 1 J/s.) If all of the light emitted has a wavelength of 525 nm, how many photons are emitted per second
The Al2O3 does not react. If the sample residue weighs 2.489 g, what is the mass fraction of Fe2O3 in the original sample?
Identify the subshell in which electrons with the quantum number n = 5, l = 4 are found. (Just write A,B, C, D, or E on the answer sheet) a) 5d b) 5p c) 5g d) 5f e) 4f
Some AgCl(s) has been placed in a beaker of water. After some time, the solubility of Ag+ and Cl- was measured to be 2.5 x 10-5 M. Determine whether the system has reached equilibrium.
What is the buffer component ratio, ([BrO-]/[HBrO]) of a bromate buffer that has a pH of 7.88. Ka of HBrO is 2.3 x 10-9
when 0.625 g of ca metal is added to 200.0 ml of 0.500 m hclaq a temperature increase of 102c is observed. assume the
if you know the amounts of acid and base components in the buffer you can use the equation to find the ph. find the ka
Isotopes of elements are atoms of the same element that vary in the: 1,number of electrons associated with the nucleus. 2,number of neutrons in the nucleus. 3,number of atoms in a molecule. 4,number of protons in the nucleus.
the chromatographic paper in the spot testing chromatogram. predict the effect of this procedural change on the solution of the cation in the standard mixture
A piece of galena has a volume of 5.4 cm3. If the density of galena is 7.5 g/cm3, what is the mass (in kg) of that piece of galena?
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