Reference no: EM13503256

1. Please reduce following data for Methyl Ethyl Ketone (1) and Toluene (2) at 50oC:

P /kPa	x1	y1
12,30( P2sat)	0.0000	0.0000
15.51	0.0895	0.2716
18.61	0.1981	0.4565
21.63	0.3193	0.5934
24.1)1	0.4232	0.6815
25.92	15 119	0.7440
27.96	0,6096	0.8050
30.12	0.7135	0.8639
31.75	0.7934	0.904A
34.15	0.911)2	0.9590
36.09(P1sat)	1.00(x)	1.0000

By plotting ln(γ₁) and In(γ₂) and G^E/(x₁x₂RT) against xl Discuss significance of activity coefficients at infinite dilutions and evaluate values of A12 and A21 in:

G^E / x₁x₂RT = A₂₁x₁ + A₁₂x₂

2. A researcher mixed two liquids A and B in equal volumetric amount (100 ml each) with the objective to form 200 ml of a solution. However, it was later found that the net volume was somewhat less than expected. Calculate this net decrease in the volume. Also this researcher then decided to simply add more volume of liquid B until the total volume became exactly 200 ml - how much liquid B the researcher had to add'?

Use V_A = 40.727 cm³ mol and V_B = 18.068 cm³ mol^-1 with corresponding partial molar volumes as 38.632 cm³ mo1^-1 and 17.765 cm³ mol^-1 respectively. Remember net volume of a solution is algebraic sum of partial molar volumes. Also do not forget that liquid arc "not" ideal gases - their volumes fractions and mole fractions arc different. Molecular weight of A and B are 40.727 and 180.068 respectively.