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1) Almost all amino acids are chiral. The body only uses L amino acids, and proteins are chains of amino acids that in the most simple sense fold up into a single structure by themselves when they are formed. Do you think a cell could live with all D (the opposite of L) amino acids, explain your logic. When I ask 'live', I mean could the organism/cell be composed completely of D amino acids and live
2) When an amino acid's side chain, such as aspartic acid, has a pKa, that pKa is not the same if the amino acid occurs on the interior of a protein. Why would the pKa of a side chain of an Asp occuring on the inside of a protein be different from an Asp on the outside of a protein?
Please provide web references.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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