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Consider an electrochemical cell that consists of two graphite electrodes separated by a large distance in an aqueous electrolyte. A potential of 1 V is applied between the two electrodes. Assume no Faradaic processes occur. a) If the electrolyte is pure water, assuming the polarization of water molecules can be ignored, draw the potential profile across the electrochemical cell. b) If the solution contains 0.1 M KCl, draw schematics showing the distribution of molecules and ions near the two electrodes. Also draw the potential profile across the electrochemical cell. This is essentially a simple supercapacitor. Are the potential drop profiles at the two electrodeelectrolyte interfaces exactly identical? Why?
suppose you wanted to dissolve 106g of na2co3 in enough h2o to make 6.00 l of solution.a. what is the molar mass of
Set up and solve the Huckel secular equations for the pi electrons of NO3-. Express the energies in terms of the coulomb integrals alphao and alphan and the resonance integral beta. Determine the delocalization energy of the ion.
State what happens to a proton in a magnetic field when a RF signal is applied perpendicular or that magnetic field
Which basic arrangement would best accommodate three electron domains in the valence shell of a covalently bonded atom
Write an equation explaining why H2 gas is evolved when HCl is added during the workup. You may abbreviate the NaBH4 as hydride H- (hint hudride is both nucleophilic and basic)
You have a protein that undergoes conformational change from folded state(F) to unfolded state(U) depending on pH. For each state draw a graph for how scattering intensity might change with time.
If a certain reaction has a rate constant of 9.51x10-9 L mol -1 s-1 at 500K as well as a rate constant of 1.10z10-5 L mol -1 s-1 at 600K, Explain what is the value of Ea
A bag of potato chips contains 595 mL of air at 30.0 degrees celcius and a pressure of 770 mm Hg. Assuming the bag does not break, what will be its volume at the top of a mountain where the pressure is 438 mL and the temperature is 8.00 celcius?
When 75.0 grams of ammonia, 90.0 grams of carbon dioxide and 61.0 grams of water are reacted to form ammonium carbonate, what is the limiting reactant and how many grams of product will be formed
What must be the concentration of PO43- to just start precipitation of Ag3PO4 in a 0.10M AgNO3 solution?
Compute the photon wavelength in nm corresponding to the electron affinity for chlorine(349kj/mol). In what district of the electromagnetic spectrum does the wavelength fall
Calculate the pH for each of the following cases in the titration of 50.0 mL of 0.120 M HCIO (aq) with 0.120M KOH (aq)
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