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1.Helium gas is heated at constant volume from a state of 100 kPa, 300 K to 500 K. A following process expands the gas at constant pressure to four times the initial volume.a.Show the combined process on a P-V diagramb.What is the work per unit mole in the combined process?
2.A work of 2.5 kJ must be delivered on a rod from a pneumatic piston/cylinder where the air pressure is limited to 500 kPa. What diameter cylinder should I have to restrict the rod motion to maximum 0.5 m?
3.A piston cylinder contains air at 600 kPa, 290 K and a volume of 0.01 m3. A constant pressure process gives 18 kJ of work out. Find the final volume and temperature of the air.
4.A piston cylinder contains 3 kg of air at 20oC and 300 kPa. It is now heated up in a constant pressure process to 600 K.a.Find the final volumeb.Plot the process path in a P-v diagram and T-v diagram (v is the specific volume = V/m)c.Find the work in the process.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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