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What steps would you take to separate the following four organic compounds using an acid/base solvent extraction? Compounds: m-anisic acid, p-toluidine, thymol, indane
The Group 5A elements can form molecules or ions with three, five or six covalent bonds. Predict the molecular structure and hybridization of the following substances: NH3, AsCl5 and PF6-. Why doesn't NF5 or NCl6- form
One major variation of the Wittig reaction is the Wittig-Horner reaction. The Wittig-Horner reaction uses triethylphosphate P(OEt)3 instead of PPh3
Electrolysis of molten NaCl in a Downs cell is the major isolation step in the production of sodium metal. If 65.0 g of Na are obtained, how many amps are required to produce this in 7.50 hours
Compound A, C9H12, undergoes nitration to give 3 products. The 1H NMR spectrum of A shows a complex three-proton multiplet at 6.92-6.99 ? and a nine-proton singlet at 2.34 ?
The enzyme D-amino acids oxidase has a very high turnover number because the D-amino acids are potentially toxic. The Km for the enzyme is in the range of 1 to 2 mM for the aromatic amino acids and in the range of 15 to 20 mM for such amino acids ..
The density of lead is 11.3 g/mL. The water level in a graduated cylinder initially at 216 mL rises to 292 mL after a piece of lead is submerged. What is the mass in grams of the lead?
Draw a titration curve for both of these peptides. Be sure to label the axes properly, indicate the pKa values, the equivalence points and the buffering regions.
Calculate the amount of heat required to completely sublime 53.0 g of solid dry ice CO_2 at its sublimation temperature. The heat of sublimation for carbon dioxide is 32.3
A metal forms the fluoride MF2. Electrolysis of the molten fluoride by a current of 3.86 A for 16.2 minutes deposits 1.07 (backwards "g") of the metal.
Mixed Aldol Each of the following compounds can be prepared by a mixed aldol condensation reaction. Give the structure of the aldehyde and/or ketone precursors for each aldol product and formulate the reaction.
The explosive, TNT, is composed of 37.0% carbon, 2.2% hydrogen, 18.5% nitrogen and the rest oxygen. if the molar mass of TNT is 227 g/mol, what is the empirical and molecular formula for TNT?
Identify intermediate A, which has a molecular formula of C10H16O2, and give a curved-arrow mechanism for the transformation of A to the final product
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