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One mole of an ideal, monatomic gas initially at STP (Ti = 0oC, Pi =1 atm, Vi =22.4 L) experiences a reversible process in which the pressure is doubled. The nature of the process is unspecified, but ?U is 900 cal and q is 400 cal. (1 cal = 4.184 J)a.Calculate the final T and V (call them Tf and Vf), and ?H and w for the process.b.Suppose that the gas was taken to the same final state, but by a two-step process consisting first of an isobaric change and then an isothermal one, both reversible. Calculate the overall values of ?H, ?U, q and w for this sequence.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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