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My question is about problem 45a in chapter 6 of John McMurry'sOrganic Chemistry, 7th ed. In this problem, we are asked todetermine whether a substituted alkene should be designated "Z" or"E". The carbon on the right side of the double bond isconnected to a CO2H group on the top and a hydrogen atomon the bottom. However, the carbon on the left side of thedouble bond is part of a cyclohexane ring. There is a methylgroup attached to the ring, 2 carbons away from the double-bondedcarbon. The methyl group is on the same side of the doublebond as the CO2H group of the other double-bonded carbon("top").
My question is as follows. How do you assignCahn-Ingold-Prelog priorities to the substituents of a particularcarbon atom when the carbon atom in question is part of a ring? There aren't 2 different substituents! Where does the"top" substituent end and where does the "bottom" substituentend?
The combustion of propane illustrated by the following reaction releases 2428 KJ per mole of reaction. A sample of propane is burned at 59 degrees celsius and 746 mm Hg. The process produces 39.7 L of CO2(g). How much heat was released?
Calculate the molarity of a solution that is 7.00% by mass Magnesium sulfate and has a density of 1.071g/ml
The first step in industrial nitric acid production is the catalyzed oxidation of ammonia. Without a catalyst, a different reaction predominates: 4NH3(g) + 3O2(g) ? 2N2(g) + 6H2O(g) When 0.0230 mol gaseous NH3 and 0.0250 mol gaseous O2 are placed ..
Given the following reaction, if 3.00 mol of Al are placed in a reaction vessel with 6.00 mol of CO2, how many mol of Al2O3 can theoretically be produced
Calculate the enthalpy change for the reaction, assuming that the solvation enthalpies of the sugars are negligible. Draw an energy profile for the overall process.
Identify the element of Period 2 which has the following successive ionization energies, in kJ/mol. IE1: 1314, IE2: 3389, IE3: 5298, IE4: 7471, IE5: 10992, IE6: 13329, IE7: 71345, IE8: 84087.
Describe the molecule xenon trioxide, XeO3, using four possible Lewis structures, one each with zero, one, two, or three Xe---O double bonds.
Perform a t-test at the 95% confidence level to determine if the new method contains bias. What is the calculated value of t for the new method
Why is the catalyst Copper Chloride faster at the decomposition of hydrogen peroxide than Postassium Iodide and Lead Oxide
Many metals pack in cubic unit cells. The density of a metal and length of the unit cell can be used to determine the type for packing. For example, platinum has a density of 21.45 g/cm3 and a unit cell side length
the trunk remains undistrubed for 13,750 years what percentae of the original c-14 is still present ? ( half life of c-14 = 5730)
What is the pH during the titration of 25.00mL of 0.10M HAc(aq) using .10M NaOH(aq) as the titrant, after the addition of 10.0, 25.0, and 30.0ml of titrant.
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