Mixture of ethylene-propylene-ethane-extent of reaction

Reference no: EM13173595

1) Mixture of ethylene (1), propylene (2) and ethane (3) were withdrawn from a distillation column as a top product. The distillation column was operated at 150°C and 30 bar. Mole fraction of ethylene, propylene and ethane at the distillate are 0.35, 0.5 and 0.15, respectively. Determine fugacity and fugacity coefficient for all components.

2) A gas mixture containing 2 moles of nitrogen, 7 moles hydrogen and 1 mole of ammonia initially is undergoing the following reaction:

N2 +3H2 →2NH3

a) Derive an expressions for mole fractions of various components in the reaction mixture in terms of the reaction coordinate.

b) Explain how the conversion of limiting reactant is related to the extent of reaction.

c) The standard heat of formation and standard free energy of formation of ammonia at 298 K are -46100 J/mol and -16500 J/mol respectively. Calculate the equilibrium constant for the above reaction at 500 K. (Assume, the standard heat of reaction is constant in the temperature range of 298 to 500 K). Determine, whether the reaction is endothermic or exothermic.

d) For ammonia synthesis, the temperature and pressure of the reaction are 500 K and 20 bar. Determine the fractional conversion of nitrogen to ammonia at this temperature and pressure.

e) If two moles of Argon is added to the system and the conditions are same as in (d). Determine the effect of Argon on fractional conversion of nitrogen.

Reference no: EM13173595

Questions Cloud

How much of the solution is needed : A student needs 65g of butonic acid for a reaction. The student has 450g of a 43% in ethanol.

State what is the ppm of water in the ethanol sample : the current generator box was only 89.3% current efficient, losing some current. The production of the tri-iodide ion was by the same oxidation reaction as in our lab. What is the ppm of water in the 250 ml ethanol sample?

What is the percent error of the measured density : A cube of a gold with a volume of 59 cm3 has a mass of 980 g. The density of pure gold is 19.3 g/cm3. What is the percent error of the measured density?

What is the volume of air at stp that an individual breathes : The normal respiratory rate for a human being is 15.0 breaths per minute. The average volume of air for each breath is 0.505 L at 20.0°C and 9.95 x 104 Pa. What is the volume of air at STP that an individual breathes in one day (in cubic meters or..

Mixture of ethylene-propylene-ethane-extent of reaction : 1) Mixture of ethylene (1), propylene (2) and ethane (3) were withdrawn from a distillation column as a top product. The distillation column was operated at 150°C and 30 bar. Mole fraction of ethylene, propylene and ethane at the distillate are 0.35,..

What are the percentages of co2 and ne in the sample by mole : If the sample contains a combined total of 1.75 grams per mole and has a total mass of 51.0 grams, what are the percentages of CO2 and Ne in the sample by mole?

What is the internal energy of an ensemble of one mole : What is the internal energy of an ensemble of 1 mole of particles having two non-degenerate electronic energy levels separated by 1000cm^-1 at 1310K.

What is the total pressure exerted by the gas mixture : In a gas mixture, the partial pressures are nitrogen 435 , oxygen 145 , and helium 240 . What is the total pressure ( torr) exerted by the gas mixture?

How many moles of nitrate ions are present in a sample : How many moles of nitrate ions are present in a sample that contains 4.82 moles of chromium(III) nitrate, Cr(NO3)3

User Account

All Pages