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One kg mole of an ideal gas is compressed isothermally at 127 degrees C from 1 atm to 10 atm in a piston and cylinder arrangement. Calculate the entropy change of the gas, the entropy change of the surroundings and the entropy change of the "universe" resulting from the process if:
a) The process is mechanically reversible and the surroundings consist of a heat reservoir at 127 degrees C.
b) The process is mechanically reversible and the surroundings consist of a heat reservoir at 27 degrees C.
c) The process is mechanically irreversible, requiring 20% more work than the mechanically reversible compression and the sorroundings consist of a heat reservoir at 27 degrees C?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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