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LNG (Liquefied Natural Gas) is essentially methane gas cooled to -160 C at which temperature it condenses to the liquid state at a few psia above atmospheric. The density of liquid methane is about half that of water being 500 kilograms per cubic meter. The LNG is transported in spherical refrigerated containers of 35,000 m^3. Ships normallySuppose one of these containers is ruptured and the liquid methane pours into the sea.The liquid turns to gas, and the sea water is quickly cooled, probably to the freezing point of water.a. How much gas at standard conditions (0 C, 1 atmosphere) would be released in such an accident? (Assume ideal gas conditions. The molecular weight of methane is 16gms/mole. The gas constant R= 0.082 atm.liters/mole K.) You may remember that 1m^3=10^3 liters.
b. Assuming this gas expanded into a spherical bubble at these conditions what would the diameter of bubble be?
Using standard enthalpies of formation from Appendix 2A, calculate the standard reaction enthalpy for the following reaction, the final step in the production of nitric acid
what is the molar mass of the solute? The boiling point elevation constant for water is .512 C/m.
Atmospheric pressure decreases as altitude increases. In other words, there is more air pushing down on you at sea level, and there is less air pressure pushing down on you when you are on a mountain.
Calculate the change in molar Gibbs free energy of tristearin when a deep-sea creature is brought to the surface (p = 1 atm) from a depth of 1.5 km. The density of sea water is 1.03 g/cm-3.
An acid HA has Ka = 2.28 x 10 -4. The % ionisation of this acid in a 0.170 M solution of the acid in water is closest to
A sealed container of oxygen gas has a pressure of 44.2 atm at 319.0 K. If the container is cooled to 239.0 K, what is the new pressure of the gas
It is filled with helium at 23 oC and 0.991 atm and placed in an oil bath. To what temperature (oC) will the oil bath need to be heated to first open the safety valve?
A compound containing nitrogen and oxygen is decomposed in the laboratory and produces 1.78 g of nitrogen and 4.05 g of oxygen. Calculate the empirical formula of the compound.
A magnesium strip is reacted with hydrochloric acid yielding 26.8ml of hydrogen gas. hydrogen gas was collected over water at temp of 27 degres celsius and under a total pressure of 765 mmhg. calculate the mass of the magesium strip
question the reaction a 2b products was found to have the rate law rate kab2. predict by what factor the rate of
At its boiling point, the vaporization of 0.579 mol CH4 requires 4.76 kJ of heat. What is the enthalpy of vaporizating of methane?
Draw a titration curve for both of these peptides. Be sure to label the axes properly, indicate the pKa values, the equivalence points and the buffering regions.
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