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In the stratosphere, chlorine atoms catalytically destroy ozone (O3) producing the now infamous ozone hole above the Antarctic pole. An intermediate compound of this process is chlorine monoxide (ClO), before chlorine is bound and rendered inactive by the formation of chlorine nitrate (ClONO2). Perform a steady-state analysis for d[Cl]/dt and for d[ClO]/dt in the following mechanism:
Cl2 → 2 ClCl + O3 → ClO + O22 ClO →2 Cl + O2ClO + NO2 → ClONO2
Obtain expressions for the steady-state concentrations of Cl and ClO and hence for the rate of change of ozone.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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