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Important information about Identifying unknown substances
Compound A (C7H14O) burned with a yellow, nonsooty flame and did not decolorize a bromine-methylene chloride solution. It did give a positive 2,4-dinitrophenylhydrazine test, but a negative Tollens test. Treatment of the compound with lithium aluminum hydride followed by neutralization with acid, produced a Compound B, which gave a positive Lucas test in about 5 minutes. Compound B also gave a positive ceric nitrate test. The H NMR spectrum for Compound A gave the following data:
1.02 ppm 9H, singlet2.11 ppm 3H, singlet2.31 ppm 2H, singlet
Give suitable structures for compound A and B.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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