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The following information is to be used for the next two questions. Molar absorptivity data for the cobalt and nickel complexes with 2,3-quinoxalinedithiol are ?Co = 36400 and ?Ni = 5520 at 510 nm and ?Co = 1240 and ? Ni = 17500 at 656 nm. A 0.499-g sample was dissolved and diluted to 100.0 mL. A 25.0-mL aliquot was treated to eliminate interferences; after addition of 2,3-quinoxalinedithiol, the volume was adjusted to 50.0 mL. This solution had an absorbance of 0.810 at 510 nm and 0.476 at 656 nm in a 1.00-cm cell. a) Calculate the concentration of cobalt (in ppm) in the initial solution prepared by dissolving the sample. b)Calculate the concentration of nickel (in ppm) in the initial solution prepared by dissolving the sample.
A 0.4243-g sample of CaCO 3 is dissolved in 12 M HCl and the resulting solution is diluted to 250.0 mL in a volumetric flask. How many moles of CaCO 3 are used (formula mass = 1 00.1 )
You have measured the absorbance for a vitamin sample to be 1.2 at a wavelength of 264. Can you use this reading to determine the INITIAL CONCENTRATION of your vitamin sample?
Write the mechanism for the formation of 4-chlorobenzanilide from the combination of the following reagents:
Chemical Kinetics - Show that only the reactants of the slow step of a reaction are found in the rate law of the reaction - which of the two steps is slower and which substance (if any) is probably an unstable intermediate?
Consider the molecules ClF3O and BrF3O. (a) Would expect the lone pair on the central halogen to be axial or equatorial in these molecules? Explain
A precipitate resulted when the solution was treated with 6M sodium hydroxide. The precipitate dissolved in ammonia, giving a royal blue solution
The free energy change Delta Gt at 500 K is equal to 9.8x10^4 J/mol. Calculate the equilibrium constant at 500 K.
Find the activity coefficient of H+ in a solution containing 0.010M HCl plus 0.040M KClO4. What is the pH of the solution?
Its volume has been accurately determine to be 3226.7kj/m. 2.5127 gm benzoic acid are burned in a carorimter the temperatuer rises from 20.84 to 25.67degree. What is the heat capacity of the bomb.
Select the IR frequency and number of NMR signals that is diagnostic for either isomer a or isomer b. Isomer A: cyclopentanecarboxamide Isomer B: 6-hydroxyhexanenitrile
Gas chromatography. Answer the following questions about retention times of the following compounds. Given naphthalene (boiling point = 218 degrees C), phenol (boiling point =181.7 degrees C), and toluene (boiling poit = 110.6 degrees C). A) List ..
The Specific Heat of a cooling oil is 1.75 J/g. How much heat energy is neededto raise he temp of 2.72 kg of this oil from 23 C to 191 C.
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