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1. Calculate the change in pH of rainwater resulting from an increase in the Pressure of CO2 from 10^-3.5 atm to 10^-3.0 atm due to fossil fuel emissions. 2. Suppose the gas above the soda in a bottle of a soft drink is pure CO2 at a pressure of 2 atm. a. Estimate the pH of the soda. b. Calculate C_T, the total dissolved inorganic carbon. 3. Nitrogen in a wastewater treatment plant is in the form of ammonia and ammonium ion and has a total concentration of 7.1 x 10^-4 M (KH for NH3 is 57 M/atm; pKa of NH4^+ is 9.26). a. Find the fraction of the nitrogen that is in the ammonia (NH3) form (and hence strippable) as a function of pH. Include a table AND a graph. b. If the wastewater pH is raised to 10 and the atmospheric ammonia partial pressure is 5.0 x 10^-10 atm, what would be the equilibrium concentration of total nitrogen in the wastewater after air stripping?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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