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Some years ago a unique proposal was made to raise the Titanic. The plan involved placing pontoons within the ship using a surface-controlled submarine-type vessel. The pontoons would contain cathodes and would be filled with hydrogen gas formed by the electrolysis of water. It has been estimated that it would require about 7 X 108mol of H2 to provide the buoyancy to lift the ship (J. Chem. Educ., 1973, Vol. 50, 61).
(a) How many coulombs of electrical charge would be required?
(b)What is the minimum voltage required to generate H2 and O2 if the pressure on the gases at the depth of the wreckage (2 mi) is 300 atm?
(c) What is the minimum electrical energy required to raise the Titanic by electrolysis?
(d)What is the minimum cost of the electrical energy required to generate the necessary H2 if the electricity costs 85 cents per kilowatt-hour to generate at the site?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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