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CH3316 Homogeneous Catalysis
• Construct catalytic cycles using fundamental organometallic reaction steps.
• Understand how d-block metals can be used to effect catalytic transformations.
• Understand how empirical data can be used to construct catalytic cycles or identify key steps in the cycles
• Propose mechanistic details by interpreting experimental data.
• Explain chemo- regio- and stereo-selectivity in terms of a catalytic mechanism.
• Understand how knowledge of mechanism can lead to process optimisation.
• Understand the importance of the support ligand(s) and how they can be designed for function.
A sample of Au(ClO)3 is contaminated with LiClO. An acidified 0.2000 g of this mixture is treated with excess sodium iodide and subjected to iodometric titration.
You have weighed out 520 mg of methyl oleate. Knowing that the sample you received only contains 70 % of methyl oleate, how many mmole of methyl oleate did you weigh out
Assume at certain time the wave function is N for all x between values x=1cm and x=2cm. for all values of x outside the interval 1, 2 the wave function is zero.
What percentage of their offspring will be homozygous versus heterozygous?
how will the volume of a gas sample change if its temperature is increased? explain without using the ideal gas law
1- calculate the radius of a marble of mass 75.673g and density 2.443g/cm3, volume of sphere V= (4/3)?r3)
The problem: CaCO3 can be roasted to produce CaO and CO2. This reaction is carried out in a flash connected to an open-end mercury manometer when the atmospheric pressure is 754 torr
A 120 pound woman working in an office consumes about 2200 kcal/day, whereas the same woman climbing a mountain needs 3400 kcal/day.
Calculate the molar mass of a vapor that has a density of 1.58 g/L at 23.2 oC and 610. torr. 2. If the volume of a container is 39.4 L. and the container holds a gas at 13.2 oC. and 7.00x104 torr.
The equilibrium constant K for a certain reaction was measured as a function of temperature (in Kelvin). A plot of ln(K) versus 1/T for this reaction gives a straight line with a slope
The reaction:H2(g) + I2(g) to 2HI(g) has an equilibrium constant of K=54.4 at 355 degrees (C). At 355 degrees (C) and a total pressure of 0.5 atm, what are the final pressures of each gas when the reaction reaches equilibrium? (Assume you have no HI ..
Determine the of a solution that is 1.85% by mass. Assume that the solution has density of 1.01
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