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You are comparing low temperature CVD growth of metal alloys from a variety of metal-organic precursors. In a design-of-experiments exercise to do this, you measure growth rates at various temperatures. For a Cu precursor you find that the growth rate raise by a factor of 10 from 200 to 400C, while that the increase is only a factor of 5 for a Ni precursor over the same temperature range.
a) Find out the activation energies for CVD growth from each of the precursors.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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