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A compound A has prominent infrared absorptions at 1050, 1786, and 1852 cm-1 and shows a single absorption in the proton NMR spectrum at d 3.00. When heated gently with methanol, compound B, C5H8O4, is obtained. Compound B has IR absorptions at 2500-3000 (broad), 1730, and 1701 cm-1, and its proton NMR spectrum in D2O consists of resonances at d 2.7 (complex splitting) and d 3.7 (a singlet) in the intensity ratio 4:3. Give the structures A and B, omitting stereochemistry.
We place 1.32 mol PCl5 in a 1.0L flask and allow it to reach equilibrium at a given temperature. What is the final concentration of Cl2 in the flask? PCl5 = PCl3 + Cl2 K= .47
From the Mn concentrations (3.56ppm and 3.71ppm) and uncertainty
a solution of 0.64 grams of adrenaline in 36.0 grams of CCl4 elevates the boiling point by 0.49 celsius. what is the molar mass of adrenaline?
A mixture consisting of 50 grams ethanol and 50 grams water is distilled using an efficient column. How much water will remain in the distillation flask the instant all of the azeotrope has distilled?
WHen 0.075 moles of ammonium sulfate ((NH4)2SO4) are dissolved in enough water to make 337 mL of solution, how many ammonium ions are present?
A 89 L sample of dry air is cooled from 134°C to -18°C while the pressure is maintained at 2.85 atm. What is the final volume?
Compute the final temperature of the solution (assuming no heat lost to the surroundings ) the solution has a specific heat capacity = 4.18 J/°C·
the density of phosphorus vapour at 310 degrees celcius and 75 mmHg is 2.64 g/L. What is the molecular formula of the phosphorous under these conditions?
If 66.5 ml of base is required to reach the second equivalence point, what is the concentration of the acid?
Calculate the amount of heat liberated (in kJ) from 351 g of mercury when it cools from 88.0°C to 15.0°C.
explain the main concept behind the VSEPR theory of molecular shape. how do both number and type of electron pairs influence the shape of a molecule?
What volume of .250 M calcium chloride would be required to precipitate silver chloride if it is mixed with 600.0 ml of 0.650 M Silver nitrate.
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