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15.0 mL of a 0.100 M solution of malonic acid is titrated with 0.109 M NaOH.Ka1 = 1.5 x 10^-3Ka2 = 2.0 x 10^-6
a) What is the pH when 5.00 mL of base has been added?
b) What volume is required to get to the first midpoint (midpoint of the buffer region)?
c) What is the pH at the first and second midpoints?
d) What is the pH at the first equivalence point?
e) What is the pH at the second equivalence point?
Compound K reacts with ozone to give phenylacetic acid (C6H5CH2COOH), while similar treatment of L gives 2 products. One product, M, is an aldehyde with formula C7H6O; the other product is glyoxal (CHO)2. Draw the structure of compound M
Determine the activation energy for diffusing copper into gold if you know that the diffusion coefficient is 3.98 x 10-13 m2/s at 980 oC and the diffusion coefficient is 3.55 x 10-16 m2/s at 650oC.
The reaction will become more spontaneous. B) The spontaneity of the reaction will not change. C) The reaction will become less spontaneous. D) ?G will decrease. E) K will decrease.
The molar enthalpy of vaporization of carbon disulfide is 26.74 kJ/mol, and its normal boiling point is 46°C. What is the vapor pressure of CS2 at 0°C
Tenzic acid is a H2Tenz is a diprotic acid with ionization constants Ka1 = 4.1 x 10-4, Ka2 = 1.5 x 10-9. Calculate a value for the [Tenz2-] in a 0.500 molar solution of H2Tenz.
A solution containing an unknown quantity of A plus 930 nM B gave a relative detector response (peak area of A)/(peak area of B) = 1.21. Find the concentration of A in the unknown.
We do not have a reliable method for determining the number of molar equivalents of bleach being added because commercial preparations vary in concentration and "oxidizing power
What is the molarity of an aqueous solution containing 75.3 g of glucose (C6H12O6, mol wt = 180 g/mole) in 35.5 mL of solution
Formulas and constants to remember R = 1.98 cal/degree-mole ; Delta G0 = -RT lnKeq. T = 298 degrees K. How much NADH will be produced in the above reaction
what solution will have the lowest boiling point?
The heat evolved when a mole of octane undergoes complete combustion is 1303 kcal. This is called the heat of combustion. How many kcal of heat wil be generated when 148 grams of octane react with 952 grams of oxygen? Show calculations.
A student analyzed and recorded two potassium emission spectra: 1) one using 0.10 M Potassium sulfate solution; 2) one using 0.10M Potassium nitrate solution;. Determine why will significant differences be observed in the two emission spectra.
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