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Phosphoric acid is a triprotic acid (3 acidic hydrogens) with ionization constants as follows: Ka1 = 7.5 x 10^-3 , Ka2 = 6.2 x 10^-8 , Ka3 = 4.2 x 10^-13 . Phosphate buffers with pH values near 2, 7, and 12 can be prepared using the appropriate ‘phosphate' conjugate acid-base pairs. Decide which of the following 2 solutions below you would use in order to prepare a phosphate buffer assigned by your instructor. Which is (12). Predict,using the Henderson-Hasselbalch equation, what this pH should be. A. 0.10 M phosphoric acid (H3PO4) B. 0.10 M sodium dihydrogen phosphate (NaH2PO4; the monobasic salt which contains H2PO4-ions) C. 0.10 M sodium hydrogen phosphate (Na2HPO4; the dibasic salt which contains HPO42-ions D. 0.10 M sodium phosphate (Na3PO4; the tribasic salt which contains PO43-ions)
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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