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A mixture of Phe (pI 5.5), Thr (pI 6.5), Asp (pI 3.0), His (pI 7.6), and Lys (pI 9.8) at pH 9.8 is loaded on an anion-exchange column and then eluted with a pH gradient of lowering pH. what order will the aminoo acids elute? Explain.
A solution is initially 0.050M in acetate, CH3COO- (Kb = 5.6 x 10^-10). 10.0mL of 0.10 M HCl is added. The Ka for the conjugate weak acid of CH3CHOO- is 1.8 x 10^-5. Calculate the pH for this solution at equilibrium.
When measuring the boiling point of a compound, why is the micro boiling point determined at the point when the last bubble has left the bottom of the bell and the liquid begins to rise in the bell
A solution is initially 0.050M in acetate, CH3COO- (Kb = 5.6 x 10^-10). 10.0mL of 0.10 M HCl is added. Calculate Ka for the conjugate weak acid of CH3COO-
Use the van der Waals equation of state to calculate the pressure of 3.20 mol of Xe at 481 K in a 5.80-L vessel.
How many grams of ammonium sulfate are needed to make 0.3500 L solution at a concentration of 5.000M.
When 35.6 L ammonia and 40.5 L oxygen gas react at STP, NO(g) and water are produced. How many grams of NO(g) are produced assuming 100% yield?
Write the reactions for the preparation of the diaonuim salt for the coupling of the salt with the sodium salt of 2-napthol.
How many grams of sucrose must be added to 552 g of wwater to give a soution with a vapor pressure 2.0 mm Hg less than that of pure water at 200C ?( the vapor pressure of water at 200C is 17.5 mm Hg)
The heat of combustion of naphthalene (C10H8) is - 5157 kJ/mol. Using these data and data in Appendix C, calculate the heat of hydrogenation of naphthalene.
The enzyme, carbonic anhydrase, is a large zinc-containing protein with a molar mass of 3.00 × 104 g/mol. Zn is 0.218% by mass of the protein.
The normal boiling point of the liquid is 425 K. Liquid, X, and Y are all in equilibrium at 342 K and 1800 bar. Tc = 571K, Pc= 46 bar
A 3.664 g sample of a monoprotic acid was dissolved in water and required 20.27 mL of a 0.1578 M KOH solution for neutralization. what is the molar mass of the acid
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