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A piston and a piston rod are fitted inside a cylinder of length 0.508m and area 6.45 x 10^-3 m^2. Although the piston is quite thin, it weighs 9.07kg; the piston rod is 1.29 x 10 ^-3m^2 in area and weighs 4.53 kg. On top of the rod, but outside the cylinder, an 18.14kg weight is placed. Originally, gas in the cylinder above the piston is at atmospheric pressure while the piston is positioned in the middle of the cylinder. Gases in the cylinder both above and below the piston are helium and under these conditions may be considered ideal with a constant Cv = 12.6 J/mol K. The initial temperature everywhere is 311K. Assuming the cylinder, piston, and piston rod to be nonconducting and having a negligible heat capacity, discuss any heat or work interactions if the weight on top should fall off. What is the final state of the system when the piston has stopped and there is a balance of forces across the piston? Do not neglect the fact that during motion there may be some friction between moving parts. Consider cases in which the piston is (a) diathermal and (b) adiabatic.
In a beaker, I mix 50 ml of 3 M HCl with 100 ml distilled water. Both fluids are at 25 C initially. (Cp mix =. 0.985 cal/g-C) a. what is the final T.
If 3.00 g of (NH4)2SO4 is dissolved in enough water to form 200. mL of solution, what is the molarity of the solution?
How many mL of 5.0 M NaOH can be added before its buffering capacity is exhausted?
Draw a three-dimensional structure of CH3CL. Include all non-bonding pairs in your drawing. Shoe the direction of the molecular dipole and indicate bond angles.
Find the de Broglie wavelength (in nm) associated with an electron that is moving with a velocity of 1900 km/s. The electron rest mass is 9.11 x 10-31kg.
Suppose that you have 175 mL of a buffer that is 0.300 M in both benzoic acid (C6H5COOH) and its conjugate base (C6H5COO%u2013). Calculate the maximum volume of 0.250 M HCl
An acidic aqueous solution of AlBr3 is in an electrolytic cell. What reactions take place at the anode and the cathode.
compatible combination was titrated with 0.1021M standardHCl. It took 20.97mL to reach the phenolphthalein end point and 42.00mL to reach the bromocresol greenend point.
Calculate the heat absorbed by 15.0 g of water to raise its temperature from 20.0oC to 50.0oC at constant pressure. The specific heat of water is 4.18 J/g.oC
What mass of F2 is needed to produce 167 g of PF3 if the reaction has a 77.0% yield?
Nitrogen dioxide dimerizes to produce dinitrogen tetroxide. Give a possible explanation for why this reaction occurs
600 mL of water is heated from 20c to 85 c to make a cup of tea. How much heat flows into the water? NOTE: density and specific heat capacity of water 1.00g/mL and 4.18J/(g.c) respectively.
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