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1. How much heat does one mole of water release when its temperature is reversibly reduced from 350 K to 250 K at atmospheric pressure? You may assume that the heat capacities take constant values Cpl= 75.3 JK-1 and Cps = 36.8 JK-1. In addition ΔHfus = 6004 J at Tfus = 273 K. What are the enthalpy and entropy changes for the water?
2. What is the change in entropy of a system consisting of one mole of ideal gas when it is expanded isothermally and reversibly from a pressure of 6 bar to 2 bar at 275 K? What is the change of entropy of the surroundings?
Calculate the concentration (M) of sodium ions in a solution made by diluting 50.0 mL of a 0.874 M solution of sodium sulfide to a total volume of 250.0 mL
A sample containing 3.00 mol of an ideal gas at 25C is expanded isothermally and reversibly from an initial volume if 6.0L to a final volume of 24.0L. Calculate deltaG and deltaA for this process.
To prevent tank rupture during deep-space travel, an engineering team is studying the effect of temperature on gases confined to small volumes
Aspirin's mode of action is to make a covalent bond with the active site of the COX II enzyme which inactivates the enzyme. A nucleophilic histidine side chain
Write a detailed mechanism for the reaction of salicylic acid with acetic anhydride, showing clearly the function of the catalyst, sulfuric acid.
Determine the ion notation for an atom with 18 electrons and 20 protons
Determine the volume of 0.215M KOH solution required to neutralize each of the following samples of sulfuric acid. The neutralization reaction is: H2SO4(aq)+2KOH(aq)?K2SO4(aq)+2H2O(l)
Large quantities of liquefied natural gas (LNG) are shipped by ocean tanker. At the unloading port provision is made for vaporization of the LNG so that it may be delivered to pipelines as gas.
A direct current was passed through a solution containing alanine, Match the behavior with correct amino acid. The isoelectric point of histidine is 10.0.
Write the equation(s) that describe the synthesis of (NH4)2PbCl6 starting from Pb(II) [i.e Pb(NO3)2]. Hint:There is a redox reaction in the first step, where the bleach (ClO^-) is the oxidising agent.
A 1.200 gram sample of C7H6O2 was dissolved in 11.42 grams of lauric acid, and it was determined that the freezing point of the lauric acid was lowered by 1.680 Celcius.
a gas cylinder witha volume of 3.00 dm^3 contains 8.00 moles of oxygen gas at a temperature of 50.0k. what is the pressure inside the cylinder.
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