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1. How much heat does one mole of water release when its temperature is reversibly reduced from 350 K to 250 K at atmospheric pressure? You may assume that the heat capacities take constant values Cpl= 75.3 JK-1 and Cps = 36.8 JK-1. In addition ΔHfus = 6004 J at Tfus = 273 K. What are the enthalpy and entropy changes for the water?
2. What is the change in entropy of a system consisting of one mole of ideal gas when it is expanded isothermally and reversibly from a pressure of 6 bar to 2 bar at 275 K? What is the change of entropy of the surroundings?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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