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Lewis Structure: CN- Anion
(a) Draw the best Lewis dot structure for the anion CN- and indicate on the basis of formal charges whether you would expect the extra electron to be on carbon or nitrogen. Does this agree with the prediction based on electronegativity? Explain.
(b) Given the atomic energy levels for the carbon and nitrogen atoms below, draw a molecular orbital diagram for CN- anion labeling all the bonding and antibonding molecular orbitals appropriately. Fill in the electrons in the appropriate orbitals.2p __ __ __2s __1s __
C
__ __ __ 2p__ 2s__ 1s
N
(c) Do you expect CN- anion to be affected by a magnetic field? Explain your reasoning.
(d) What is the bond order of the anion CN-?
(e) What is the bond order of the neutral CN?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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