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"24.22 Researchers are proposing the development of a ‘‘nano- channel reactor'' for steam reforming of methane (CH4) to fuel- cell hydrogen gas to power microscale devices. Gas phase diffusion in nanochannel A = CH4, B= H2O A+B 20 mol% CH 4 -----------------------------> Nanochannel ( NA/NB) = 0.25 300 degrees C, 0.5 atm, 200Nm diameter As each channel diameter is so small, the gas flow is likely to be very small within a given channel. Hence, gas diffusion pro- cesses may play a role in the operation of this device, particularly during the mixing and heating steps. We are specifically inter- ested in evaluating the effective diffusion coefficient of methane gas (species A, MA 1?4 16g/g: mol) in water vapor (species B, MB 1?4 18 g/g: mol) at 3008C and 0.5 atm total system pressure. The diameter of the channel is 200nm (1x 10^9 nm = 10m) A feed gas containing 20 mol % CH4 in water vapor is fed to the nanochannel with a flux ratio NA/NB = 0:25. What is effective diffusion coefficient of CH4 in the nanochannel at the feed gas conditions? Is Knudsen diffusion important?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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