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Ethylene glycol (HOCH2CH2OH), the major substance in antifreeze, has a normal boiling point of 198 C. By comparison, ethyl alcohol (CH3CH2OH) boils at 78C at atmospheric pressure. Ethylene glycol dimethyl ether (CH3OCH2CH2OCH3) has a normal boiling point of 83 C and ethyl methyl ether (CH3CH2OCH3) has a normal boiling point of 11.
A) Explain why replacement of a hydrogen on the oxygen by CH3 generally results in a lower boiling point.
B) What are the major factors responsible for the difference in boiling points of the two ethers.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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