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2. 2.3 mol of helium at 20°C and 5.0 atm are allowed to expand reversibly and adiabatically until the pressure reaches 1.0 atm.
a. Determine Ssys separately for the volume and temperature changes and show that ?Ssys = 0 for a reversible adiabatic process.
b. If the expansion had instead occurred irreversibly against a constant external pressure of 1 atm, now what are ?Ssys, ?Ssur, and ?Suniv?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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