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The Rice-Herzfeld mechanism for the thermal decomposition of acetaldehyde (CH3CO) is the following below (10 points) (1) CH3CHO ---> CH3' + CHO' (k1) (2) CH3' + CH3CHO ---> CH4 + CH2CHO' (k2) (3) CH2CHO' --->CO + CH3' (k3) (4) CH3' + CH3' --->C2H6 (k4) Using the steady-state approximation, determine the rate of methane (CH4) formation in terms of [CH3CHO]. where ' is for radical
A tank of 10 m3 volume contains an ideal gas (CP=30 J/mol-K) at T=298 K and P=5 bar. If gas from the tank is allowed to flow through a reversible device and exhaust to the atmosphere at P=1 bar.
The wedge is connected to a pendulum and swings through an arc and hits the sample at the bottom of the arc. The sample breaks and the wedge continues its swing to a height of 0.5 m. The energy required to break the sample is closest to
Synthetic polypeptides can assume an helical structure under appropriate conditions. Indicate whether polylysine and polyglutamate form an helix
Write the ground-state electron configurations for the following elements. (Type your answer in noble gas notation using the format [Ar] 4s2 3d10 4p2 for [Ar]4s23d104p2.)
What would the molar concentration of the tree sap have to be to achieve this pressure on a day when the temperature is 28?
the first order decomposition of N2O5 at 238 K has a rate constant of 1.70 * 10-3. If the initial concentration of N2O5 is 2.88M,
Draw appropriate Lewis structure and VSEPR structure for oxalate anion. What is the O-C-O bond angle? What is the C-C-O bond angle? What is the hybridization of each carbon? On which atoms does the negative charge reside? Draw all resonance struct..
A volume of 80.0 ml of H2O is initially at room temperature (22.0 C). A chilled steel rod at 2.00 C is placed in the water. If the final temperature of the system is 21.1 C , what is the mass of the steel bar?
What are the probable classes of hydrocarbon or hydrocarbon derivative (i.e.: alkane, alkene. ketone. ester. organic halide, etc...) in each of the following
A solution containing Pt4+ is electrolyzed with a current of 5.00 A. How long will it take to plate out 77% of the platinum in 0.50 L of a 0.010 M solution of Pt4+?
aluminum may be formed by the passage of 60,714 C through an electrolytic cell that contains a molten aluminum salt.
If the amount of Hg in an industrial-waste pond is 0.39 micrograms (ug)/mL, how much Hg is present in (kg) if the pond has a surface area (m^2) and an average depth of 35 ft?
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