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For each stereoisomer, draw the structure. Be sure to specify the stereochemistry via wedge-and-dash bonds.
1. (S)-5,5-dibromo-3-fluoro-2-methyl-3-hexanol
2. (R)-5,5-dibromo-3-fluoro-2-methyl-3-hexanol
Calculate the standard Gibbs free energy and the equilibrium constant at 298 K and at 400. K for the reaction PbO(s) + CO(g) ? Pb(s) + CO2(g).
Solid CrF3 contains a Cr(III) ion surrounded by six F- ions in an octahedral geometry, all at distances of 190 pm. However, MnF3 is in a distorted geometry with Mn-F distances of 179, 191, and 209 pm (two of each). Suggest an explanation.
At 25C the acid dissociation constant for formic acid is 6.9x10-4. Calculate DG for this reaction. R=8.31x10-3 kj/K) Can you please help me work this problem.
The pKa values of a compound with two ionizable groups are pKa1 = 4.10 and pKa2 between 7 and 10. A biochemist has 10 mL of a 1.0 M solution of this compoud at a pH of 8.00. She adds 10.0 mL of 1.00 M HCl,
Calculate the pH at the beginning of a titration of 50.00 of 0.005M HA (Ka=2.0*10^-2) with NaOH solution. If the quadratic equation is assumed to be accurate
How many grams of dipotassium phthalate must be added to 750 ml of 0.5 M phthalic acid to give a buffer of pH 5.75
Assuming that the Pauli exclusion principle remains valid in the distant universe, what is the maximum number of electrons that can populate a given orbital there.
write an equation for the acid-base reaction between nitrous acid and hydroxide ion. why does the equilibrium favor the products
Explain why the H-H distances determined for coordinated dihydrogen by X-ray diffraction are always significantly shorter than
When an aqueous solution of K2CrO4 is mixed with an aqueous solution of AgNO3, a brown precipitate forms. a) Write the balanced molecular equation (including all products and phases) for this reaction.
Calculate deltaS, deltaStotal, and deltaSsurroundings when the volume of 84.0g of CO initially at 298K and 1.00bar increases by a factor of four in (a) an adiabatic reversible expansion, (b) an expansion againt Pexternal=0, and (c) an isothermal r..
despite its name, is at least mildly toxic. The properly balanced mixture reacts to form K2CO3, N2, H2O and CO2. Write the balanced reaction and determine the mass of kno3 that should be mixed with 1.4 g of sugar to produce optimally balanced rock..
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