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An unavoidable side reaction of alkyl halides with active metals which lowers the yield of Grignard reagents is called coupling.
2 RX + Mg --------> R-R + MgX2
Although the mechanism of the coupling process is not well understood, it is known that ratre appears to depend on the square of the concentration of the halide. With this in mind, explain the reason for the sequaence of addition of the ether solution employed at the beginning of the formation of the Grignard reagent in the experimental procedure above.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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