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While cleaning the organic stockroom, a student found a bottle of ethanol labeled "Denatured with Benzene." He decided to determine the concentration of benzene in the ethanol by acquiring the UV spectrum of the liquid in a 2.0 cm cell. The spectrum exhibited an absorption band at 260 nm which is attrbutable to benzene, and the absorbance of this band was 0.69. In a reference source, the student found that the molar absorptivity of this benzene band in ethanol was 230 M-1cm-1. Show how the student calculated the concentration of the benzene in the ethanol.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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